Chemistry · fundamentals

Atoms

What atoms are made of, how we count their particles, and how they become ions.

What is an atom?

Atom: the smallest unit of an element that keeps the element's properties.

  • Nucleus: at the centre, contains protons and neutrons
  • Electron cloud: electrons around the nucleus
  • Mostly empty space
  • Size: about \(10^{-10}\) m (1 ångström)

Not to scale: if the atom were a stadium, the nucleus would be a marble at the centre.

Subatomic particles

ParticleChargeMassLocation
Proton+11 amu (atomic mass unit)Nucleus
Neutron0 (neutral)1 amuNucleus
Electron−1~0.0005 amu (negligible)Electron cloud / orbitals

Atomic number and mass number

Atomic number · Z
  • Number of protons
  • Defines the element
  • Never changes for an element
Mass number · A
  • Protons + neutrons
  • \(A = Z + N\), where \(N\) = neutrons

Notation: \( {}^{A}_{Z}\mathrm{X} \), e.g. \( {}^{12}_{\;6}\mathrm{C} \) for carbon-12

Neutral atoms

Neutral atom: number of protons = number of electrons.

Ions

Ion: an atom that has gained or lost electrons.

Cation: positive ion

  • Lost electrons
  • More protons than electrons
  • Example: Na⁺ (11 protons, 10 electrons)

Anion: negative ion

  • Gained electrons
  • More electrons than protons
  • Example: Cl⁻ (17 protons, 18 electrons)

Build an atom

protonneutronelectron
Protons
Neutrons
Electrons

Exercises

Answer each question before revealing it. The atom builder can check many of them.

Exercises · part 1

What is an atom?

The smallest unit of an element that retains its properties

What are the three main subatomic particles?

Protons, neutrons, electrons

Where are protons located?

In the nucleus

What is the charge of a neutron?

Zero (neutral)

Exercises · part 2

What is atomic number?

The number of protons in the nucleus; it defines the element

What is mass number?

Total protons plus neutrons, A = Z + N

Carbon has 6 protons and 6 neutrons. What is its mass number?

A = 6 + 6 = 12 (carbon-12)

Does atomic number change in chemical reactions?

No: atomic number defines the element's identity

Exercises · part 3

What makes an atom neutral?

Number of protons equals number of electrons

Sodium has 11 protons. How many electrons does neutral sodium have?

11 electrons

What is a cation?

A positive ion: an atom that lost electrons

What is an anion?

A negative ion: an atom that gained electrons

Exercises · part 4

An oxygen atom gains 2 electrons. What is the ion?

O²⁻ (oxide ion, an anion)

Magnesium loses 2 electrons. What is the ion?

Mg²⁺ (magnesium ion, a cation)

An ion has 12 protons and 10 electrons. What is its charge?

+2 (12 − 10 = +2)

Which particle determines element identity?

The proton (atomic number)

Exercises · part 5

Aluminium has atomic number 13 and mass number 27. How many neutrons?

N = A − Z = 27 − 13 = 14 neutrons

An atom has 8 protons, 8 neutrons and 8 electrons. What element is it?

Oxygen (atomic number 8)

What is its mass number?

A = 8 + 8 = 16 (oxygen-16)

Is this atom neutral or charged?

Neutral (protons = electrons)

Exercises · part 6

Why is atomic mass not exactly a whole number?

It is a weighted average over the element's isotopes, so it includes fractional contributions

Which particle has negligible mass?

The electron (about 1/2000 of a proton's mass)

Iron loses 3 electrons. Write the ion symbol.

Fe³⁺ (iron(III) cation)

Chlorine gains 1 electron. Write the ion symbol.

Cl⁻ (chloride anion)

Exercises · part 7

What is mostly empty in an atom?

The space between the nucleus and the electron cloud

What is a typical atomic diameter?

About 10⁻¹⁰ m (1 ångström)

What holds electrons around the nucleus?

Electrostatic attraction (opposite charges attract)

Can the number of neutrons change without changing the element?

Yes: that creates isotopes (same element, different mass)